You will have to map the physicalPath to a virtualPath. Here is how you would do that.
public static Configuration OpenConfigFile(string configPath)
{
var configFile = new FileInfo(configPath);
var vdm = new VirtualDirectoryMapping(configFile.DirectoryName, true, configFile.Name);
var wcfm = new WebConfigurationFileMap();
wcfm.VirtualDirectories.Add("/", vdm);
return WebConfigurationManager.OpenMappedWebConfiguration(wcfm, "/");
}
let me know.